I just read an article on spiegel.de (paywall) about what one needs to use 5G+, aka Voice over New Radio (VoNR). VoNR seems to be an optional feature a phone can provide in addition to 5G that routes phone calls to LTE.
They mention that Vodafone Germany says the following phones support VoNR:
iPhone 13 bis 16, das Samsung Galaxy S21 bis S24, das Google Pixel 7 bis 9 und das Xiaomi Mi 11 5G
Check the developer settings there you can probably enable, however of it works…for me its gryed out but enables although I dont even have 5G. Network Telefonica.
To check if it works it might help to call this number
The second is also linked by the first. The articles do not seem to be available in any other language, so please use a translator like DeepL or Google Translator if you want to kno more. To wet your appetite, here are the titles in English
5G Standalone now Available: These are the Benefits
5G SA: 5G Standalone sets new Benchmarks